Mots-clé :

Mots-clé :

Summary :

Résumé :

Because of the increasing need for ever better performing materials endowed with specific properties, macromolecular engineering has become a useful tool for designing well-architectured polymers (telomers, telechelics, stars, dendrimers, alternating, block- and graftcopolymers). These polymers are nowadays seeing an enormous growth. Among them, fluoropolymers are seen as high value added materials in many applications ranging from surfactants, optical fibers, biomaterials, coatings, to membranes for fuel cells. Indeed, the relationship between structure of the monomer to the properties of the polymers is of increasing interest so that these properties are tuned for the most appropriate applications. As most fluoropolymers are prepared from radical synthesis, this book devotes various parts on the use of the controlled radical (or pseudo-living) polymerisation of fluoromonomers leading to discoveries of thermoplastic elastomers or original surfactants for polymerisation in supercritical CO2. Well-Architectured Fluoropolymers: Synthesis, Properties and Applications, is composed of five chapters starting with a general introduction outlining basic concepts. Emphasis is placed on recent developments, and each chapter describes comprehensive techniques of synthesis of well-defined fluorotelomers or polymers, their properties, characterisations, and their applications, for immediate use by today’s engineers, industrial and academic scientists, and researchers. The book has been arranged to enable self-managed reading and learning. It is both a source of data and a reference.

Mots-clé :

Mots-clé :

Summary :

Fluoropolymers display a wide range of remarkable properties and are used in a number of applications including high performance elastomers, thermoplastics, coatings for optical fibers, and hydrophobic and lipophobic surfaces. Fluorinated Polymers: Synthesis, Properties, Processing and Simulation covers the fundamentals of different fluorinated polymers. Topics include the kinetics of homopolymerisation and copolymerization, process chemistry, and controlled radical co-polymerisation techniques. Written by internationally recognized academic and industrial contributors, the book will be of interest to those in industry and academia working in the fields of materials science, polymer chemistry and energy applications of polymers. Together with Fluorinated Polymers: Applications, these books provide a complete overview of different fluorinated polymer materials and their uses.  

Mots-clé :

Summary :

This book covers the recent applications of fluoropolymers. Examples include materials for energy applications such as fuel cell membranes, lithium ion batteries and photovoltaics, as well as high-tech areas such as aerospace and aeronautics, automotives, building industries, textile finishings and electronics. Written by internationally recognized academic and industrial contributors, the book will be of interest to those in industry and academia working in the fields of materials science, polymer chemistry and energy applications of polymers. Together with Fluorinated Polymers: Synthesis, Properties, Processing and Simulation, these books provide a complete overview of different fluorinated polymer materials and their uses.

Mots-clé :

Summary :

Description

Fluoropolymers are very unique materials. Since the middle of the twentieth century fluoropolymers have been used in applications where a wide temperature range, a high resistance to aggressive media, excellent tribological characteristics, and specific low adhesion are required. Today, researchers turn to fluoropolymers to solve new challenges and to develop materials with previously unattainable properties. Opportunities for Fluoropolymers: Synthesis, Characterization, Processing, Simulation and Recycling covers recent developments in fluoropolymers, including synthesis of new copolymers, strategies for radical polymerization of fluoromonomers (conventional or controlled; RDRP), and the modification of fluoropolymers to achieve desired material characteristics. This volume in the Progress in Fluorine Science series is ideal for researchers and engineers who want to learn about the synthetic strategies, properties, and recycling of these special polymers, as well as industrial manufacturers who are interested in achieving new product characteristics in their respective industries.

Table of Contents 1. Semi–fluorinated Aromatic Ether Polymers via Step-growth Polymerization of Fluoroalkenes Ganesh Narayanan and Dennis W. Smith, Jr., Department of Chemistry and The Marvin B. Dow Advanced Composites Institute, Starkville, MS-39762, United States. 2. Iodine transfer emulsion polymerizations of vinylidene fluoride F. Brandl, J. Schwaderer, M. Drache, S. Beuermann (Claustal Univ., Germany)   3. Fluorinated compounds as mediators in controlled radical polymerization M. Edeleva (Russian Insttitute Novosibirsk, Russia 4. Specifics of the Mn2(CO)10 Photomediated Synthesis of PVDF Block Copolymers Vignesh Vasu, Joon-Sung Kim, Abhirup Dutta and A. Asandei University of Connecticut, USA) 5. Fluoropolymers by initiated Chemical Vapor Deposition (iCVD) K. K. Gleason (MIT, USA) 6. Supramolecular structure of gamma-irradiated polytetrafluoroethylene S.A. Khatipov, V.M. Buznik (Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, and National University of Oil and Gas «Gubkin University” Russia 7. Preparation and applications of fluoroalkyl end-capped oligomeric composites Hideo Sawada (Hirosaki Univ., Japan) 8. Fluoropolymers for water/oil separation R. Bongiovanni, A. Vitale (Politecnico Torino, Italy) 9. PVDF-based Shape Memory Materials G. A. Eken, M.H. Acar (Istanbul Technical Univ., USA) 10. Manufacturing Strategies in Fluorinated Polymers and Composites J. M. McCollum University of Colorado, Colorado Springs, USA 11. Mineralization of Fluoropolymers Using Subcritical Water Hisao Hori (Kanagawa Univ., Japan) 12. Regioisomerism defects in PVDF: Impact on structural properties Armand Soldera (University of Sherbrooke, Canada)  

Mots-clé :

Summary :

Description

Fluoropolymers are unique materials. Since the middle of the twentieth century fluropolymers have been used in applications where a wide temperature range, a high resistance to aggressive media, excellent tribological characteristics, and specific low adhesion are required. Today, researchers turn to fluoropolymers to solve new challenges and to develop materials with previously unattainable properties. Fascinating Fluoropolymers and Their Applications covers recent developments of fluoropolymer applications in energy, optical fibers, blood substitutes, textile coatings, membranes and other areas, written by experts in these fields. This volume in the Progress in Fluorine Science series is ideal for researchers and engineers who want to learn about the technology and applications of these special polymers, as well as industrial manufacturers who are interested in achieving new product characteristics in their respective industries.

Table of Contents

1. Piezoelectric poly(vinylidene fluoride) based materials: recent progress, challenges and opportunities C. M. Costa, V. Cardoso, P. Martins, D. M. Correia, V. Correia, C. Ribeiro, P. M. Martins, S. Lanceros-Méndez (Universidade do Minho, Braga, Portugal, Basque Center for Materials and IKERBASQUE, Spain)

2. Electroactive polymers K. Loos (Univ. of Groningen, The Nederlands) Piezoelectricity and ferroelectricity

3. Electroactive fluoropolymers and polyamides L. Zhu (Case Western Reserve Univ., USA)

4. Redox active fluoropolymer H. Sun (South Dakota Univ., USA)

5. Perfluoropolymers for membrane application M. Galizia, Y. Okamoto (New-York Univ. Tandon School of Engineering, USA)

6. Gas and vapor transport, thermodynamics of sorption and free volume in fluorinated and perfluorinated polymers N. Belov, A. Alentiev, Y. Yampolskii (A.V. Topchiev Institute of Petrochemical Synthesis (Moscow), Russia)

7. Thermal Transitions and Mechanical Relaxations in Perfluorinated Ionomers C. M. Orsino, R. B. Moore (Virginia Tech., USA) Introduction to Perfluorinated Ionomers

8. Self-organizing semifluorinated polymers for organic electronics D. Pospiech, D. Jehnichen, C. Horn, M. Plötner (Dresden, Germany)

9. Fluorinated Thermosetting Resins for Photonics and Microelectronics Dreyer, C., Schrader.  Frauhaufer & Technical University of Applied Sci, Wildau, Germany

10. Fluoropolymer Architectural Textiles. Production, processing and characterisation A. Sonnendecker, D. W. Viljoen, B. Ameduri, P. L. Crouse (University Pretoria, South Africa and Institute Charles Gerhardt, France)

11. Organofluorine compounds in artificial blood circulation systems Oleg V. El’kin, Andrejv N. Bushuev, IvanV. Tolstobrov, SergeyV. Fomin, E.S. Shirokova, A.V. Sazanov, V.A. Kozvonin, Denis A. Kozulin  (Vyatka State University, Russia)

12.  Elastomeric Composites Based On Propylene Oxide Rubber With High Filling Degree With Ultrafine Polytetrafluoroethylene for Operation in Cold Climates Portnyagina V.V., Petrova N.N., Morozov A.V., Mukhin V.V.

Mots-clé :

Mots-clé :

Summary :

Volume E10 Organo-Fluorine Compounds from the acclaimed Houben-Weyl series is now available in a WORKBENCH EDITION. A unique resource in the field, this 5-volume set provides a comprehensive treatise of the preparation and reactivity of organo-fluorine compounds presented in the high-quality format synonymous with the Houben-Weyl series. Now available in a workbench edition to give a prime source of detailed information directly in the lab.

Houben-Weyl Vol. E10 Organo-Fluorine Compounds is a critical survey of the academic and patent literature, organized in a systematic and structured way and presented in 5 volumes. In Volume E10a Section A details the diverse range of fluorinating agents used to make C-F bonds. In Volumes E10b/1 and E10b/2 Section B describes in detail methods for the synthesis of fluorinated compounds from organo-fluorine precursors (the building block approach), while in Section C are outlined general reactions and reactivity of organo-fluorides. A comprehensive index is provided in Volume E10c/1 and E10c/2.

Houben-Weyl Vol. E10 Organo-Fluorine Compounds is written by leading experts in the field and will prove to be an invaluable tool for the student and researcher alike well into the next millennium. For full information on the complete Houben-Weyl series, please visit the Houben-Weyl Homepage

Mots-clé :

Résumé :

This volume brings together contributions by leading researchers covering a wide scope so characteristic of fluorine chemistry. It is a monograph of historical character comprising personalized accounts of progress and events in areas of particular interest. There is also much to interest and instruct chemists from other disciplines as a good proportion of the chapters contain a considerable amount of 'hard' referenced information relating to modern organic, organoelemental and inorganic chemistry. Historians of chemistry and technology will no doubt be tempted to dip into this book, and surely whoever addresses the task of commemorating Moissan's achievement at the 150-years stage will bless us all in some measure for its existence.

Mots-clé :

Mots-clé :

Mots-clé :

Mots-clé :

Summary :

This book is dedicated to all who have contributed to the acquisition of knowledge concerning the chemistry of fluorine and its compounds. It is published to commemorate the centenary of the first isolation of elemental fluorine by Henri Moissan in 1886. His notable achievement provides the justification of this book, but over the years many chemists, ranging from famous to obscure, have worked in the rather special and exciting field of fluorine chemistry. All have contributed something to the vast body of information now available, and the scope of this book is a tribute to their collective endeavours. The book is in two parts. The first addresses the history of the development of fluorine chemistry from the 18th century to the key period centered after World War II; this includes Moissan's own accomplishments. The second comprises reviews by acknowledged experts of the major branches of the field; these update the earlier accounts and show how the subject has developed, from difficult, experimental beginnings, into a coherent sub-discipline of chemistry.

Résumé :

Destiné aux chimistes, cet ouvrage tente de faire un tour d’horizon des diverses applications des composés fluorés en chimie bioorganique et médicinale. Les propriétés spécifiques des composés fluorés, leurs modes de préparation, le rôle de la présence de fluor dans les molécules biologiques et les différentes classes de cescomposés sont analysés précisément. Les principaux médicaments existant ou en développement font l’objet du dernier chapitre.

Mots-clé :

Mots-clé :

Summary :

Mots-clé :

Mots-clé :

Summary :

Foreword, O. Boltalina, T. Nakajima

1. Electronic properties and applications of fluorofullerenes, O.V. Boltalina

2. Synthesis and Isolation of trifluoromethylfullerenes, B.W. Larson, S.H. Strauss, O.V. Boltalina

3. Thirteen Decakis(trifluoromethyl)decahydro(C60-Ih)[5,6]fullerenes (C₆₀(CF3)₁₀): Structures and Structure-Related Properties of the Largest Set of Fullerene(X)nIsomers, E.V. Bukovsky, B.W. Larson, T.T. Clikeman, Y.S. Chen,A.A. Popov, O.V. Boltalina, S.H. Strauss

4. Trifluoromethylated Corannulene Derivatives: A.A. Popov

5. Fluorinatione / Defluorination and Fluorine Storage Properties of Single-Wall Carbon Nanotubes and Carbon Nanohorns, Y. Hattori, H. Touhara

6. Synthesis and characterization of fluorinated carbon fibers and nanotubes,Y. S. Lee

7. Perfluoroalkylated PAH n-type semiconductors: theory and experiment, H. Sun, J.H. Kramer

8. Electronic properties of fluorinated graphene, L.G. Bulusheva, A.V. Okotrub

9. Nature of C-F bonds in fluorinated carbons, M. Dubois, K. Guérin, A. Hamwi, A. Vinogradov

10. Preparation and application of fluorine-carbon and fluorine-oxygen carbon materials

11. Intercalation chemistry and application of B/C/N materials to secondary batteries, Y. Matsuo

12. Structures of highly fluorinated compounds of layered carbon, M. Kawaguchi, K. Yamada, H. Ishikawa

13. Lithium – graphite fluoride battery: history and fundamentals, T. Nakajima

14. Fluorinated nanocarbons for lubrication, P. Tomas, P. Bilas, A. Molza, L. Legras, J.L. Mansot, K. Guérin, M. Dubois

15. Perfluoropolyether-functionalized carbon-based materials and their applications, M Sansotera, M. Gola, W. Navarrini

16. Nanoeletronics Based on Fluorinated graphene, K.I. HO, C.S. Lai, C.Y. Su

Index

Mots-clé :

Mots-clé :

Summary :

Description

A must-have resource for all the researchers working in the organofluorine and related fields

This timely two-volume set uniquely focuses on emerging fluorinated motifs beyond R-CF3 and R-F, like R-CF2H, R-OCF3, R-SCF3 and R-SF5. It also offers descriptions of the properties, synthesis, and applications of these emerging fluorinated motifs in order to help readers design new chemical entities, while providing new interest for researchers in organofluorine chemistry and new tools for those in other areas.

Emerging Fluorinated Motifs: Synthesis, Properties and Applications begins with a description of carbon-linked fluorine-containing groups that include monofluoromethyl and difluoromethyl groups. It then details combinations of heteroatoms, Oxygen, Sulfur, Selenium, Nitrogen, and Phosphorus with fluorine-containing groups, outlining subsections of the most popular current motifs. Fluoroalkyl ethers, thioethers, and the recent blossoming of the SF5 unit is covered. Other chapters look at: selenium-linked fluorine-containing motifs; construction of N?CF2H, N?CF3, N?CH2CF3 motifs; and the synthesis and applications of P¿Rf-containing molecules.

-Focuses on the synthesis, properties, and applications of emerging fluorinated motifs
-Covers carbon-linked fluorine-containing motifs, oxygen-linked fluorine-containing motifs, sulfur-linked fluorine-containing motifs, and more
-Appeals to academic and industrial researchers working in organic chemistry, medicinal chemistry, food chemistry, and materials science
-Edited by world-renowned experts in organofluorine chemistry

Emerging Fluorinated Motifs is intended for academic research institutes, university libraries, researchers, graduate students, postdoctors, and researchers in the chemical industry.